Journal of Nuclear Science, Engineering and Technology (JONSAT)
In cooperation with the Iranian Nuclear Society

Sorption of Metal Ions on Synthetic Organoinorganic Ion Exchanger Polyacrylonitril-Ti(IV) Tungstophosphate

Document Type : Research Paper

Authors

A Heidary
S.J Ahmadi
M.R Asadi
F Asgharizadeh
P Ashtari
Abstract
In this study two Polyacrylonitril-Ti(IV) tungstophosphate organo-inorganic ion exchangers with different molar ratios have been synthesized. These ion exchangers have been characterized by FT-IR, X- ray diffraction, TG, SEM and CHNSO techniques and their cation exchange capacity has been measured by continuous method. Distribution coefficients (Kd) for metal ions and radionuclides were determined by batch method andwith these ion exchangers, separation of metal ions was achieved on a glass column.

Highlights

 

 

  1. 1.    INTERNATIONAL ATOMIC ENERGY AGENCY, “Guide to the safe handling of radioactive waste at nuclear power plants,” Technical Reports Series, No. 198, IAEA, VIENNA (1980).

 

  1. 2.    R.A. Leonard, C. Conner, M.W. Liberatore, J. Sedlet, S.B. Aase, G.F. Vandegrift, L.H. Delmau, P.V. Bonnesen, B.A. Moyer, Sep. Sci. Thechnol, 36, 743-766 (2001).

 

  1. 3.    F. Helfferich, Ion exchange, McGraw-Hill Co. Inc. N.Y (1962).

 

  1. 4.    R.W. Grimshaw and C.E. Harland, “Ion exchange: Introduction to theory and practice,” The Chemical Society, London (1975).

 

  1. 5.    R. KUNIN, “Elements of Ion exchange,” Reinhold Pub. Co, N.Y (1960).

 

  1. 6.    B. Tremillon, Le role et 1' utilisation de la complexation dans les applications des resines echangeuses d ' ions,” Z. Anal. Chem, 236, 472-498 (1968).

 

  1. 7.    C.B. Amphlett, “Inorganic Ion exchangers,” Elsevie Pub. Co, N.Y (1964).

 

  1. 8.    V. Kourim, O. Vojtech, At. Energy Rev, 12, 215-273 (1974).

 

  1. 9.    F. Sebesta, J. John, A. Mort, K. Stamberg, SAN95-2729 (1995).

 

10. “Waste management and disposal,” Report of INFCE Working Group 7 Published by IAEA, VIENNA (1980).

11. “Nuclear power waste Technology,” Sponsored by the ASME Nuclear Engineering Division.

 

12. “Radioactive waste management,” Proceedings of an International Conference, Seattle, 16-20 May 1983, Vol. 2, IAEA, Vienna (1984).

 

13. Zia Mahmood Siddiqi, Deepak Pathania, Journal of Chromatography A, 987, 147-158 (2003).

 

14. C. Ferragina, P. Cafarelle, A. De Stefanis, R.D. Rocco, P. Glannoccaro, Mater. Res. Bull. 36 (2001) (1799).

 

15. M. Qureshi, N. Zehra, S.A. Nabi, V. Kumar, Talanta 20, 609 (1973).

 

16. H. Sepehrian, R. Yavari, M. Ghannadi Maragheh1, S.W. Husain, Radiochim. Acta 96, 105-109 (2008).

 

17. H. Sepehrian, M. Ghannadi-Maragheh, S. Waqif-Husain, R. Yavari, A.R. Khanchi, “Journal of Radioanalytical and Nuclear Chemistry,” Vol. 275, No. 1, 145–153 (2008).

 

18. L.A. Kovaleva, M.A. Fodotov, V.A. Grigoriev, C.L. Hill, Inorg. Chem. 39, 3828 (2000).

 

19. H. Yamazaki, Y. Inou, N. Kikuchi, H. Kurihara, Bull. Chem. Soc. Jpn. 6, 566 (1991).

 

20. H. Sepehrian, A.R. Khanchi, M.K. Rofouei, S. Waqif, “Husain Journal of the Iranian Chemical Society,” Vol. 3, No. 3, September, 253-257 (2006).

Keywords

Ion Exchanger
Polyacrylonitrile-Ti(IV) Tungstophosphate
Metal Ions
Cation Exchange Capacity
Separation
Batch Method
Distribution Coefficient

  1.  

     

    1. 1.    INTERNATIONAL ATOMIC ENERGY AGENCY, “Guide to the safe handling of radioactive waste at nuclear power plants,” Technical Reports Series, No. 198, IAEA, VIENNA (1980).

     

    1. 2.    R.A. Leonard, C. Conner, M.W. Liberatore, J. Sedlet, S.B. Aase, G.F. Vandegrift, L.H. Delmau, P.V. Bonnesen, B.A. Moyer, Sep. Sci. Thechnol, 36, 743-766 (2001).

     

    1. 3.    F. Helfferich, Ion exchange, McGraw-Hill Co. Inc. N.Y (1962).

     

    1. 4.    R.W. Grimshaw and C.E. Harland, “Ion exchange: Introduction to theory and practice,” The Chemical Society, London (1975).

     

    1. 5.    R. KUNIN, “Elements of Ion exchange,” Reinhold Pub. Co, N.Y (1960).

     

    1. 6.    B. Tremillon, Le role et 1' utilisation de la complexation dans les applications des resines echangeuses d ' ions,” Z. Anal. Chem, 236, 472-498 (1968).

     

    1. 7.    C.B. Amphlett, “Inorganic Ion exchangers,” Elsevie Pub. Co, N.Y (1964).

     

    1. 8.    V. Kourim, O. Vojtech, At. Energy Rev, 12, 215-273 (1974).

     

    1. 9.    F. Sebesta, J. John, A. Mort, K. Stamberg, SAN95-2729 (1995).

     

    10. “Waste management and disposal,” Report of INFCE Working Group 7 Published by IAEA, VIENNA (1980).

    11. “Nuclear power waste Technology,” Sponsored by the ASME Nuclear Engineering Division.

     

    12. “Radioactive waste management,” Proceedings of an International Conference, Seattle, 16-20 May 1983, Vol. 2, IAEA, Vienna (1984).

     

    13. Zia Mahmood Siddiqi, Deepak Pathania, Journal of Chromatography A, 987, 147-158 (2003).

     

    14. C. Ferragina, P. Cafarelle, A. De Stefanis, R.D. Rocco, P. Glannoccaro, Mater. Res. Bull. 36 (2001) (1799).

     

    15. M. Qureshi, N. Zehra, S.A. Nabi, V. Kumar, Talanta 20, 609 (1973).

     

    16. H. Sepehrian, R. Yavari, M. Ghannadi Maragheh1, S.W. Husain, Radiochim. Acta 96, 105-109 (2008).

     

    17. H. Sepehrian, M. Ghannadi-Maragheh, S. Waqif-Husain, R. Yavari, A.R. Khanchi, “Journal of Radioanalytical and Nuclear Chemistry,” Vol. 275, No. 1, 145–153 (2008).

     

    18. L.A. Kovaleva, M.A. Fodotov, V.A. Grigoriev, C.L. Hill, Inorg. Chem. 39, 3828 (2000).

     

    19. H. Yamazaki, Y. Inou, N. Kikuchi, H. Kurihara, Bull. Chem. Soc. Jpn. 6, 566 (1991).

     

    20. H. Sepehrian, A.R. Khanchi, M.K. Rofouei, S. Waqif, “Husain Journal of the Iranian Chemical Society,” Vol. 3, No. 3, September, 253-257 (2006).

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