Document Type : Research Paper
Authors
Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, AEOI, P.O.Box: 11365-8486, Tehran - Iran
Abstract
Khoshoumi Anomaly 6 is a significant uranium deposit located in the Bafq-Saghand metallogenic belt within the Central Iran zone. The gneiss serves as the primary host for uranium mineralization in block 1 of Khoshoumi Anomaly 6. Field emission electron microscopy studies have identified two stages of uranium mineralization within the area: primary mineralization (hypogene) and uranyl silicate (supergene). Primary uranium minerals found in the hypogene zone include uraninite, with minor amounts of thorouraninite, brannerite, and uranothorite. Uranyl silicate mineralization is observed along fractures in the form of boltwoodite and soddyite. Over time, boltwoodite undergoes alteration into sodium-boltwoodite and uranophane. Field evidence and mineralogical studies suggest that meteoric fluids, with a neutral to alkaline pH and low temperature, played a role in leaching uranium, silicon, potassium, sodium, and calcium from the gneiss. These elements were then deposited along fractures as uranyl silicate minerals, accompanied by calcite, clay, and chlorite. The presence of calcite alongside uranyl silicates indicates the transport of uranium in the form of uranyl carbonate complexes within the fluid.
Highlights
- Abd El-Naby H.H. Genesis of Secondary Uranium Minerals Associated with Jasperoid Veins, El Erediya Area, Eastern Desert Egypt. Mineralium Deposita. 2008;43(8):933-944. doi: 10.1007/s00126-007-0171-1.
- Abd El-Naby H.H. High and Low Temperature Alteration of Uranium and Thorium Minerals, Um Ara Granites, South Eastern Desert, Egypt. Ore Geology Review. 2009;35:436-446. doi: 10.1016/j. oregeorev.2009.02.006.
- Abd El-Naby H.H. Role of Argillic Alteration in Uranophane Precipitation along Shear Zones of the Gattar Granites, Eastern Desert, Egypt. Journal of King Abdulaziz University: Earth Sciences. 2009;20(2):45-69.
- Abd El-Naby H.H. Role of Geochemical Alteration on the Formation of Secondary Zr- and U-bearing Minerals in El Atshan Trachyte, Central Eastern Desert Egypt. Mineralogical and Petrological Sciences. 2009;104(1):37-51. doi: 10.2465/jmps. 080506.
- Abdalla H.M, Ishihara S, Matsueda H, Abdel-Monem A.A. On the albite-enriched granitoids at UmAra area, Southeastern Desert, Egypt: I. Geochemical, ore potentiality and fluid inclusion studies. Geochemical Exploration. 1996;57:127-138. doi: 10.1016/S0375-6742(96)00029-5.
- Gaafar I, Cuney M, Gawad A.A. Mineral Chemistry of Two-mica Granite Rare Metals: Impact of Geophysics on the Distribution of Uranium Mineralization at El Sela Shear Zone Egypt. Open Journal of Geology. 2014;4:137-160. doi: 10.4236/ ojg.2014.44011.
- Shalaby M.H, Abu Zeid E.K, Mahdy N.M. On the Petrogenesis and Evolution of U-rich Granite: Insights from Mineral Chemistry Studies of Gattar Granite, North Eastern Desert Egypt. Arabian Journal of Geosciences. 2015;8(6):3565-3585. doi: 10.1007/ s12517-014-1466-z.
- Ibrahim M.E, Saleh G.M, Dawood M.I, Kamar M.S, Saleh S.M, Mahmoud M.A, El- Tohamy A.M. Rare Metals Mineralization in Pegmatite at Abu Rusheid Area, South Eastern Desert Egypt. Mining Science. 2017;3(1):44-63. doi: 10.20431/2454-9460.0301004.
- Dawood Y.H, Abd El-Naby H.H. Genesis of Uranyl Mineralization in the Arabian Nubian Shield: A Review. Asian Earth Sciences. 2022;225:105047. doi: 10.1016/j.jseaes.2021.105047.
- Catalano J.G, Heald S.M, Zachara J.M, Brown G.E. Spectroscopic and Diffraction Study of Uranium Speciation in Contaminated Vadose Zone Sediments from the Hanford Site, Washington State. Environmental Science and Technology. 2004;38:2822-2828. doi: 10.1021/es049963e.
- Finch R.J, Ewing R.C. The Corrosion of Uraninite under Oxidizing Conditions. Nuclear Materials. 1992;190:133-156. doi: 10.1016/0022-3115(92) 90083-W.
- Wronkiewicz D.J, Bates J.K, Gerding T.J, Veleckis E, Tani B.S. Uranium Release and Secondary Phase Formation during Unsaturated Testing of Uranium Dioxide at 90°C. Nuclear Materials. 1992;190:107-127. doi: 10.1016/0022-3115(92)90081-U.
- Wronkiewicz D.J, Bates J.K, Wolf S.F, Buck E.C. Ten-Year Results from Unsaturated Drip Tests with UO2 at 90°C: Implications for the Corrosion of Spent Nuclear Fuel. Nuclear Materials. 1996;238:78-95. doi: 10.1016/S0022-3115(96)00383-2.
- Dawood Y.H, Abd El-Naby H.H, Ghaleb B. U-series Isotopic Composition of Kasolite Associated with Aplite-Pegmatite at Jabel Sayid, Hijaz region, Kingdom of Saudi Arabia. Arabian Journal of Geosciences. 2014;7:2881-2892. doi: 10.1007/ s12517-013-0963-9.
- Samani B. Saghand Formation, a Riftogenic Unit of Upper Precambrian in Central Iran. Journal of Geosciences. 1993;6:32-45 [In Persian].
- Forster H, Jafarzadeh A. The Bafq Mining District in Central Iran a Highly Mineralized Infra-Cambrian Volcanic Field. Economic Geology. 1994;89:1697-1721. doi: 10.2113/gsecongeo.89.8.1697.
- OECD-NEA/IAEA. Uranium 2005: Resources, Production and Demand. A Joint Report by the Organization for Economic Co-Operation and Development (OECD) of Nuclear Energy Agency and the International Atomic Energy Agency. 2005.
- Khoshnoodi K, Ziapour S, Yazdi M, Cuney M. Mineralogy of Various Types of Th-U-REE Mineralisation in the Iron Oxide- Apatite Deposits of the Bafq District, Central Iran. Applied Earth Science. 2023;132:1-15. doi: 10.1080/25726838. 2022.2147300.
- Khoshnoodi K, Ziapour S, editors. Mineralization potential of radioactive elements in iron ore deposits, Kashmar- Kerman Tectonic Zone. Proceeding of the 42nd National Geosciences Congress; 2024; Tehran, Iran [In Persian].
- Khoshnoodi K, Yazdi M, Ghannadi M, Ziapour S, Deymar S, Behzadi M. Formation and Evolution of Th-REE Mineralizing Fluids at the Kiruna-Type Choghart Iron Oxide-Apatite Deposit, Central Iran: Insights from Fluid Inclusions and H-C-O Isotopes. Geological Journal. 2022;57(6):2144-2159. doi: 10.1002/gj.4399.
- Madankav Company. Report on Estimation and Evaluation of Uranium Deposit in Block1 of Khoshoumi Area in the Detailed Phase. 2011 [In Persian].
- Yassaghi A, Masoodi M. A Metamorphic Core Complex Model for the Host of Uranium Mineralization in the Khoshoumi Mountain, Central Iran. Resource Geology. 2011;61(3):259-269. doi: 10.1111/j.1751-3928.2011.00162.x.
- Heidaryan F. A Study on Mineralization U, REE and Related Processes in Anomaly No.6 Khoshoumi Area, Central Iran. Journal of Nuclear Science, Engineering and Technology. 2005;34:47-52 [In Persian].
- Samani B, Honarmand M, editors. Uranium Mineralization and Exploration Capability in the Khoshoumi Exploratory Area (Central Iran). Proceeding of the Second National Conference of Geology and Mineral Exploration; 2016; Kerman, Iran [In Persian].
- Ramezani J, Tucker R.D. The Saghand Region, Central Iran: U-Pb Geochronology, Petrogenesis and Implication for Gondwana Tectonics. American Journal of Science. 2003;303(7):622-665. doi: 10.2475/ajs.303.7.622.
- Whitney D.L, Evans D.W. Abbreviations for names of rock-forming minerals. American Mineralogist. 2010; 95:185–187. Doi: 10.2138/am.2010.3371.
- Raslan M, Ali M. Mineralogy and Mineral Chemistry of Rare-Metal Pegmatites at Abu Rusheid Granitic Gneisses, South Eastern Desert Egypt. Geologija. 2011;53(2):205-222. doi: 10.5474/geologija.2011. 016.
- Saleh G.M, Abdallah S.A, Abbas A.A, Dawood N.A, Rashed M.A. Uranium Mineralization of Wadi Sikait Mylonites, Southeastern Desert Egypt. Geology and Mining Research. 2012;3(5):86-104. doi: 10.5897/ JGMR10.035.
- Dawood H.Y, Harbi H.M, Abd El-Naby H.H. Genesis of Kasolite Associated with Aplite-Pegmatite at Jabel Sayid, Hijaz Region, Kingdom of Saudi Arabia. Asian Earth Sciences. 2010;37:1-9. doi: 10.1016/j.jseaes.2009.05.007.
- El-Kammar A.M, Salman A.E, Shalaby M.H, Mahdy A.I. Geochemical and Genetical Constraints on Rare Metals Mineralization at the Central Eastern Desert of Egypt. Geochemical Journal. 2001;35(2):117-135. doi: 10.2343/geochemj.35.117.
- Isobe H, Ewing R.C, Murakami T. Alteration of Uranium Minerals in the Koongarra Deposit, Australia: Unweathered Zone. Journal of Nuclear Materials. 1994;190:174-187. doi: 10.1016/0022-3115(92)90085-Y.
- Ragnarsdottir K.V, Charlet L. Uranium Behaviour in Natural Environments. In: Cotter-Howells JD, Cambellm LS, Valsami-Jones E, Batchelder M, editors. Environmental Mineralogy: Microbial Interactions, Anthropogenic Influences, Contaminated Land and Waste management. London: The Mineralogical Society of GB, Alden Press, Oxford. 2000;245-289. doi: 10.1180/MSS.9.14.
- Saleh G.M, Kamar M.S. Geochemical Characteristics and Radioactive Elements Estimation along Trenches of Um Ara Area, South Eastern Desert, Egypt. Geoinformatics and Geostatics: An Overview. 2018;6(2):1-16. doi: 10.4172/2327-4581.1000178.
- Prikryl J.D. The Thermodynamics of Uranophane Dissolution and Growth in CaCl2-SiO2(AQ) Test Solutions. Center for Nuclear Waste Regulatory Analyses. 2008.
- Finch R, Murakami T. Systematics and Paragenesis of Uranium Minerals. In: Burns PC, Finch R, editors. Uranium: Mineralogy, Geochemistry, and the Environment. Washington DC: Mineralogical Society of America. 1999;91-179.
- Shvareva T.Y, Mazeina L, Gorman-Lewis D, Burns P.C, Szymanowski J.E.S, Fein J.B, Navrotsky A. Thermodynamic characterization of boltwoodite and uranophane: Enthalpy of formation and aqueous solubility. Geochimica et Cosmochimica Acta. 2011;75:5269-5282. doi: 10.1016/j.gca.2011.06.041.
- Dawood Y.H. Mineral Chemistry and Genesis of Uranyl Minerals Associated with Psammitic Gneisses, Abu Rusheid Area, South Eastern Desert of Egypt. Earth Science. 2010;21(1):137-169.
- Stohl F.V, Smith D.K. The Crystal Chemistry of the Uranyl Silicate Minerals. American Mineralogist. 1981;66:610-625.
- Wang Z, Ulrich K.U, Pan C, Giammar D.E. Measurement and Modeling of U (IV) Adsorption to Metal Oxide Minerals. Environmental Science and Technology Letters. 2015;2(8):227-232. doi: 10.1021/acs.estlett.5b00156.
- Bone S.E, Dynes J.J, Cliff J, Bargar J.R. Uranium (IV) Adsorption by Natural Organic Matter in Anoxic Sediments. Proceedings of the National Academy of Sciences. 2017;114(4):711-716. doi: 10.1073/pnas.1611918114.
- Cumberland S.A, Douglas G, Grice K, Moreau J.W. Uranium Mobility in Organic Matter-rich Sediments: A Review of Geological and Geochemical Processes. Earth Science Reviews. 2016;159:160-185. doi: 10.1016/j.earscirev.2016.05.010.
Keywords
- Abd El-Naby H.H. Genesis of Secondary Uranium Minerals Associated with Jasperoid Veins, El Erediya Area, Eastern Desert Egypt. Mineralium Deposita. 2008;43(8):933-944. doi: 10.1007/s00126-007-0171-1.
- Abd El-Naby H.H. High and Low Temperature Alteration of Uranium and Thorium Minerals, Um Ara Granites, South Eastern Desert, Egypt. Ore Geology Review. 2009;35:436-446. doi: 10.1016/j. oregeorev.2009.02.006.
- Abd El-Naby H.H. Role of Argillic Alteration in Uranophane Precipitation along Shear Zones of the Gattar Granites, Eastern Desert, Egypt. Journal of King Abdulaziz University: Earth Sciences. 2009;20(2):45-69.
- Abd El-Naby H.H. Role of Geochemical Alteration on the Formation of Secondary Zr- and U-bearing Minerals in El Atshan Trachyte, Central Eastern Desert Egypt. Mineralogical and Petrological Sciences. 2009;104(1):37-51. doi: 10.2465/jmps. 080506.
- Abdalla H.M, Ishihara S, Matsueda H, Abdel-Monem A.A. On the albite-enriched granitoids at UmAra area, Southeastern Desert, Egypt: I. Geochemical, ore potentiality and fluid inclusion studies. Geochemical Exploration. 1996;57:127-138. doi: 10.1016/S0375-6742(96)00029-5.
- Gaafar I, Cuney M, Gawad A.A. Mineral Chemistry of Two-mica Granite Rare Metals: Impact of Geophysics on the Distribution of Uranium Mineralization at El Sela Shear Zone Egypt. Open Journal of Geology. 2014;4:137-160. doi: 10.4236/ ojg.2014.44011.
- Shalaby M.H, Abu Zeid E.K, Mahdy N.M. On the Petrogenesis and Evolution of U-rich Granite: Insights from Mineral Chemistry Studies of Gattar Granite, North Eastern Desert Egypt. Arabian Journal of Geosciences. 2015;8(6):3565-3585. doi: 10.1007/ s12517-014-1466-z.
- Ibrahim M.E, Saleh G.M, Dawood M.I, Kamar M.S, Saleh S.M, Mahmoud M.A, El- Tohamy A.M. Rare Metals Mineralization in Pegmatite at Abu Rusheid Area, South Eastern Desert Egypt. Mining Science. 2017;3(1):44-63. doi: 10.20431/2454-9460.0301004.
- Dawood Y.H, Abd El-Naby H.H. Genesis of Uranyl Mineralization in the Arabian Nubian Shield: A Review. Asian Earth Sciences. 2022;225:105047. doi: 10.1016/j.jseaes.2021.105047.
- Catalano J.G, Heald S.M, Zachara J.M, Brown G.E. Spectroscopic and Diffraction Study of Uranium Speciation in Contaminated Vadose Zone Sediments from the Hanford Site, Washington State. Environmental Science and Technology. 2004;38:2822-2828. doi: 10.1021/es049963e.
- Finch R.J, Ewing R.C. The Corrosion of Uraninite under Oxidizing Conditions. Nuclear Materials. 1992;190:133-156. doi: 10.1016/0022-3115(92) 90083-W.
- Wronkiewicz D.J, Bates J.K, Gerding T.J, Veleckis E, Tani B.S. Uranium Release and Secondary Phase Formation during Unsaturated Testing of Uranium Dioxide at 90°C. Nuclear Materials. 1992;190:107-127. doi: 10.1016/0022-3115(92)90081-U.
- Wronkiewicz D.J, Bates J.K, Wolf S.F, Buck E.C. Ten-Year Results from Unsaturated Drip Tests with UO2 at 90°C: Implications for the Corrosion of Spent Nuclear Fuel. Nuclear Materials. 1996;238:78-95. doi: 10.1016/S0022-3115(96)00383-2.
- Dawood Y.H, Abd El-Naby H.H, Ghaleb B. U-series Isotopic Composition of Kasolite Associated with Aplite-Pegmatite at Jabel Sayid, Hijaz region, Kingdom of Saudi Arabia. Arabian Journal of Geosciences. 2014;7:2881-2892. doi: 10.1007/ s12517-013-0963-9.
- Samani B. Saghand Formation, a Riftogenic Unit of Upper Precambrian in Central Iran. Journal of Geosciences. 1993;6:32-45 [In Persian].
- Forster H, Jafarzadeh A. The Bafq Mining District in Central Iran a Highly Mineralized Infra-Cambrian Volcanic Field. Economic Geology. 1994;89:1697-1721. doi: 10.2113/gsecongeo.89.8.1697.
- OECD-NEA/IAEA. Uranium 2005: Resources, Production and Demand. A Joint Report by the Organization for Economic Co-Operation and Development (OECD) of Nuclear Energy Agency and the International Atomic Energy Agency. 2005.
- Khoshnoodi K, Ziapour S, Yazdi M, Cuney M. Mineralogy of Various Types of Th-U-REE Mineralisation in the Iron Oxide- Apatite Deposits of the Bafq District, Central Iran. Applied Earth Science. 2023;132:1-15. doi: 10.1080/25726838. 2022.2147300.
- Khoshnoodi K, Ziapour S, editors. Mineralization potential of radioactive elements in iron ore deposits, Kashmar- Kerman Tectonic Zone. Proceeding of the 42nd National Geosciences Congress; 2024; Tehran, Iran [In Persian].
- Khoshnoodi K, Yazdi M, Ghannadi M, Ziapour S, Deymar S, Behzadi M. Formation and Evolution of Th-REE Mineralizing Fluids at the Kiruna-Type Choghart Iron Oxide-Apatite Deposit, Central Iran: Insights from Fluid Inclusions and H-C-O Isotopes. Geological Journal. 2022;57(6):2144-2159. doi: 10.1002/gj.4399.
- Madankav Company. Report on Estimation and Evaluation of Uranium Deposit in Block1 of Khoshoumi Area in the Detailed Phase. 2011 [In Persian].
- Yassaghi A, Masoodi M. A Metamorphic Core Complex Model for the Host of Uranium Mineralization in the Khoshoumi Mountain, Central Iran. Resource Geology. 2011;61(3):259-269. doi: 10.1111/j.1751-3928.2011.00162.x.
- Heidaryan F. A Study on Mineralization U, REE and Related Processes in Anomaly No.6 Khoshoumi Area, Central Iran. Journal of Nuclear Science, Engineering and Technology. 2005;34:47-52 [In Persian].
- Samani B, Honarmand M, editors. Uranium Mineralization and Exploration Capability in the Khoshoumi Exploratory Area (Central Iran). Proceeding of the Second National Conference of Geology and Mineral Exploration; 2016; Kerman, Iran [In Persian].
- Ramezani J, Tucker R.D. The Saghand Region, Central Iran: U-Pb Geochronology, Petrogenesis and Implication for Gondwana Tectonics. American Journal of Science. 2003;303(7):622-665. doi: 10.2475/ajs.303.7.622.
- Whitney D.L, Evans D.W. Abbreviations for names of rock-forming minerals. American Mineralogist. 2010; 95:185–187. Doi: 10.2138/am.2010.3371.
- Raslan M, Ali M. Mineralogy and Mineral Chemistry of Rare-Metal Pegmatites at Abu Rusheid Granitic Gneisses, South Eastern Desert Egypt. Geologija. 2011;53(2):205-222. doi: 10.5474/geologija.2011. 016.
- Saleh G.M, Abdallah S.A, Abbas A.A, Dawood N.A, Rashed M.A. Uranium Mineralization of Wadi Sikait Mylonites, Southeastern Desert Egypt. Geology and Mining Research. 2012;3(5):86-104. doi: 10.5897/ JGMR10.035.
- Dawood H.Y, Harbi H.M, Abd El-Naby H.H. Genesis of Kasolite Associated with Aplite-Pegmatite at Jabel Sayid, Hijaz Region, Kingdom of Saudi Arabia. Asian Earth Sciences. 2010;37:1-9. doi: 10.1016/j.jseaes.2009.05.007.
- El-Kammar A.M, Salman A.E, Shalaby M.H, Mahdy A.I. Geochemical and Genetical Constraints on Rare Metals Mineralization at the Central Eastern Desert of Egypt. Geochemical Journal. 2001;35(2):117-135. doi: 10.2343/geochemj.35.117.
- Isobe H, Ewing R.C, Murakami T. Alteration of Uranium Minerals in the Koongarra Deposit, Australia: Unweathered Zone. Journal of Nuclear Materials. 1994;190:174-187. doi: 10.1016/0022-3115(92)90085-Y.
- Ragnarsdottir K.V, Charlet L. Uranium Behaviour in Natural Environments. In: Cotter-Howells JD, Cambellm LS, Valsami-Jones E, Batchelder M, editors. Environmental Mineralogy: Microbial Interactions, Anthropogenic Influences, Contaminated Land and Waste management. London: The Mineralogical Society of GB, Alden Press, Oxford. 2000;245-289. doi: 10.1180/MSS.9.14.
- Saleh G.M, Kamar M.S. Geochemical Characteristics and Radioactive Elements Estimation along Trenches of Um Ara Area, South Eastern Desert, Egypt. Geoinformatics and Geostatics: An Overview. 2018;6(2):1-16. doi: 10.4172/2327-4581.1000178.
- Prikryl J.D. The Thermodynamics of Uranophane Dissolution and Growth in CaCl2-SiO2(AQ) Test Solutions. Center for Nuclear Waste Regulatory Analyses. 2008.
- Finch R, Murakami T. Systematics and Paragenesis of Uranium Minerals. In: Burns PC, Finch R, editors. Uranium: Mineralogy, Geochemistry, and the Environment. Washington DC: Mineralogical Society of America. 1999;91-179.
- Shvareva T.Y, Mazeina L, Gorman-Lewis D, Burns P.C, Szymanowski J.E.S, Fein J.B, Navrotsky A. Thermodynamic characterization of boltwoodite and uranophane: Enthalpy of formation and aqueous solubility. Geochimica et Cosmochimica Acta. 2011;75:5269-5282. doi: 10.1016/j.gca.2011.06.041.
- Dawood Y.H. Mineral Chemistry and Genesis of Uranyl Minerals Associated with Psammitic Gneisses, Abu Rusheid Area, South Eastern Desert of Egypt. Earth Science. 2010;21(1):137-169.
- Stohl F.V, Smith D.K. The Crystal Chemistry of the Uranyl Silicate Minerals. American Mineralogist. 1981;66:610-625.
- Wang Z, Ulrich K.U, Pan C, Giammar D.E. Measurement and Modeling of U (IV) Adsorption to Metal Oxide Minerals. Environmental Science and Technology Letters. 2015;2(8):227-232. doi: 10.1021/acs.estlett.5b00156.
- Bone S.E, Dynes J.J, Cliff J, Bargar J.R. Uranium (IV) Adsorption by Natural Organic Matter in Anoxic Sediments. Proceedings of the National Academy of Sciences. 2017;114(4):711-716. doi: 10.1073/pnas.1611918114.
- Cumberland S.A, Douglas G, Grice K, Moreau J.W. Uranium Mobility in Organic Matter-rich Sediments: A Review of Geological and Geochemical Processes. Earth Science Reviews. 2016;159:160-185. doi: 10.1016/j.earscirev.2016.05.010.