مجله علوم، مهندسی و فناوری هسته‌ای

جذب‌زیستی Th(ІV)، V(V) و Fe(ІІІ) از پساب واقعی فرایند ترسیب شیمیایی توریم توسط جلبک قهوه‌ای سیستوسریا ایندیکای آمایش شده با کلسیم: مدل‌سازی نمودارهای شکست در ستون بستر ثابت و مطالعه مکانیسم جذب

نوع مقاله : مقاله پژوهشی

نویسندگان

مهدی امیری 1
علیرضا کشتکار 2
سیدمحمدعلی موسویان 1

1 دانشکده‌ مهندسی شیمی، دانشگاه تهران، صندوق پستی: 4563-11155 ،تهران ـ ایران

2 پژوهشکده چرخه سوخت هسته‌ای، پژوهشگاه علوم و فنون هسته‌ای، سازمان انرژی اتمی ایران، صندوق پستی: 8486-11365، تهران- ایران

https://doi.org/10.24200/nst.2024.1528
چکیده
در این کار پژوهشی توانایی درشت جلبک قهوه­‌ای سیستوسریا ایندیکا از خانواده فائوفیتا و آمایش شده با کلسیم برای جذب توریم (IV)، وانادیم (V) و آهن (III) از پساب واقعی فرایند ترسیب شیمیایی توریم در یک ستون­ بستر ثابت با ارتفاع cm ۲۵/5 و قطر cm ۵/1 مورد بررسی قرار گرفت. نتایج تجربی نشان داد که در جذب توریم (IV) از محلول خوراک‌­های دوجزیی توریم- وانادیم و توریم - آهن، رقابت بین یون‌­های توریم (IV) و وانادیم (V) قابل‌توجه‌­تر از رقابت بین یون‌­های توریم (IV) و آهن (III) است. هم‌­چنین در جذب توریم، وانادیم، آهن به‌­طور هم‌زمان از پساب واقعی ظرفیت جذب زیستی توریم (IV)، وانادیم (V) و آهن (III) به ترتیب برابر با ۶۰/۱۰۴، ۱۵/۲۴ و mg/g ۳۹/۱۷ به دست آمد که نشان می‌دهد میل ترکیبی یون‌­های توریم (IV) به جلبک سیستوسریا ایندیکای آمایش شده با کلسیم بیش‌­تر از یون‌­های آهن (III) و وانادیم (V) است. نمودارهای شکست جذب با استفاده از مدل‌­های بوهارت - آدامز، توماس، یون - نلسون، بلتر، دز - رسپانس اصلاح شده، گمپرتز و گمپرتز اصلاح شده مدل‌سازی شد. نتایج نشان داد که مدل گمپرتز اصلاح شده تطابق بهتری با داده­‌های تجربی دارد. هم‌­چنین، آزمایش تبدیل فوریه فروسرخ (FTIR) و اندازه‌گیری غلظت کلسیم در پساب واقعی نشان داد که گروه‌­های عاملی هیدروکسیل، آمین، آمید، متیلن، کربوکسیل و سولفات بیش‌­ترین سهم را در سازوکار تبادل یونی با یون‌­های توریم (IV)، وانادیم (V) و آهن (III) دارند.

کلیدواژه‌ها

جذب زیستی چند جزیی
جلبک قهوه‌ای
ستون بستر ثابت
نمودار شکست
مدل تجربی

عنوان مقاله English

Th(ІV), V(V), and Fe(ІІІ) biosorption from real wastewater of thorium chemical precipitation process by Ca-pretreated Cystoseria indica alga: breakthrough curves modeling in a fixed bed column and biosorption mechanism study

نویسندگان English

M. Amiri 1
A.R. Keshtkar 2
M.A. Moosavian 1
1 Department of Chemical Engineering, University of Tehran, P.O.Box: 11155-4563, Tehran - Iran
2 Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, AEOI, P.O.Box: 11365-3486, Tehran - Iran
چکیده English

This research examined how Cystoseria indica brown macroalgae of the Phaophyta family can be pre-treated with calcium to sorb Th(IV), V(V), and Fe(III) from real wastewater resulting from the thorium chemical process using a fixed bed column whose bed height was 5.25 cm and diameter was 1.5 cm. It was found that the competition between Th(IV) and V(V) ions is significant in Th(IV) biosorption from three-component feed solutions of Th(IV) - V(V) and Th(IV) - Fe(III). The biosorption capacity of Th(IV), V(V), and Fe(III) from real wastewater was also 104.60, 24.15, and 17.39 mg/g, respectively. It shows that Th(V) ions have higher affinity to Ca-pretreated Cystoseria indica algae than Fe() and V(V) ions. The biosorption breakthrough curves were modeled using Bohart-Adams, Thomas, Yoon-Nelson, Belter, adapted dose-response, Gompertz, and modified Gompertz models. The results showed that the modified Gompertz model better agreed with the experimental data. The Fourier transform infrared (FTIR) analysis and calcium concentration determination in real wastewater indicated that functional groups such as hydroxyl, amine, amide, methylene, carboxyl, and sulfate were most likely to participate in the ion exchange mechanism with Th(*V), V (V) and Fe(III) ions.

کلیدواژه‌ها English

Multi-component biosorption
Brown alga
Fixed-bed column
Breakthrough curve
Empirical model
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