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بررسی رفتار جذبی یون اورانیم از محلول آبی بر روی رزین XAD-4 آغشته شده با عامل کمپلکس کننده اسیدی

نوع مقاله : مقاله پژوهشی

نویسنده

پژوهشکده چرخه سوخت هسته‌ای، پژوهشگاه علوم و فنون هسته‌ای، سازمان انرژی اتمی ایران، صندوق پستی: 8486-11365، تهران- ایران

چکیده

از مهم‌­ترین آلاینده‌­های پایدار و غیرقابل تجزیه فلزات سنگین هستند، که از سمی‌­ترین آلاینده‌­ها در محیط زیست به‌شمار می‌روند. بنابراین حذف این آلاینده‌­ها از اهمیت خاصی برخوردار است. اورانیم به عنوان یکی از فلزات سنگین، یک رادیونوکلئید طبیعی است که به دلیل سمیت جدی و خاصیت پرتوزایی دارای اثرات مخرب بر روی سلامت انسان و محیط زیست می‌باشد. در این پژوهش رزین آمبرلیت XAD-4 آغشته شده با لیگاند باز شیف بیس 2-هیدروکسی بنزآلدهید 1و2-دی آمینو اتان (L2H) برای جذب اورانیم از محلول آبی به کار برده شد. تأثیر پارامترهای مؤثر مانند pH فاز آبی، زمان تماس، مقدار جاذب و وابستگی دمایی فرایند مورد بررسی قرار گرفتند. نتایج نشان داد که 98‌% یون‌­های اورانیم در شرایط بهینه 5/5pH، مقدار جاذب 1/0 گرم، زمان تماس 60 دقیقه و دمای 25 درجه سانتی‌­گراد، یون اورانیم با غلظت اولیه 20 میلی‌­گرم بر لیتر از 20 میلی‌­لیتر محلول آبی جذب می‌­شود. مقایسه درصد جذب رزین آغشته­ نشده با رزین آغشته ­شده با لیگاند باز شیف نشان می­‌دهد که نمودار جذب یون اورانیم در مقابل pH به سمت مقادیر pH پایین‌­تر (تقریباً 1 5/0ΔpH) تغییر می‌­کند و رفتار جذبی رزین در 5/5pH با افزایش میزان جذب از 52‌% به 98‌% بهبود می‌­یابد. داده‌­های سینتیکی و جذبی به ترتیب با معادله شبه مرتبه دوم و هم‌­دمای فروندلیچ به خوبی مطابقت دارند. بررسی ترمودینامیکی نیز نشان داد که فرایند جذب یون‌ مورد مطالعه بر مبنای آنتروپی است.

کلیدواژه‌ها

عنوان مقاله [English]

Investigation of the adsorption behavior of uranium ion from aqueous solution on the impregnated XAD-4 resin with acidic complexing agent

نویسنده [English]

  • Z. Shiri-Yekta

Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, AEOI, P.O.Box: 11365-8486, Tehran - Iran

چکیده [English]

One of the most problematic persistent and non-degradable pollutants are heavy metals, which are among the most toxic pollutants in the environment. Therefore, removing these pollutants is of particular importance. Uranium, as one of the heavy metals, is a natural radionuclide that harms human health and the environment. This is due to its serious toxicity and radiation properties. In this research, Amberlite XAD-4 resin impregnated with bis-2-hydroxybenzaldehyde 1,2-diaminoethane (H2L) Schiff base ligand was used for uranium adsorption from aqueous solution. The effect of effective parameters such as aqueous phase pH, contact time, amount of adsorbent and temperature dependence on the process was investigated. The results showed that 98% of uranium ions were absorbed under the optimal conditions of pH5.5, adsorbent amount 0.1 g, contact time 60 min. From 20 mL of aqueous solution at 25 C, uranium ions with a concentration of 20 mg/L were quantitatively removed. Comparing the adsorption percentage of non-impregnated resin with impregnated resin with Schiff base ligand shows a shift in uptake of uranium ions vs. pH curves towards lower pH values (about ΔpH0.51) and the adsorption behavior of the resin at pH5.5 improves with increasing adsorption from 52% to 98%. The kinetic and adsorption data are in good agreement with the pseudo-second-order equation and Freundlich isotherm, respectively. A thermodynamic analysis also revealed that the ion adsorption process is entropy-based.

کلیدواژه‌ها [English]

  • Uranium
  • Adsorption
  • XAD-4 resin
  • Complexing
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مجله علوم، مهندسی و فناوری هسته‌ای
دوره 45، شماره 2 - شماره پیاپی 108
تیر 1403
صفحه 115-124
فایل ها
هم رسانی
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