نوع مقاله : مقاله پژوهشی

نویسندگان

پژوهشکده چرخه سوخت هسته‌ای، پژوهشگاه علوم و فنون هسته‌ای، سازمان انرژی اتمی ایران، صندوق پستی: 8486-11365، تهران- ایران

چکیده

در این پژوهش، رفتار هیدرودینامیکی ستون پرشده همزن‌دار حاوی بخش‌های هم‌زده و پرشده با پرکن‌های نامنظم مورد بررسی قرار گرفت. ارزیابی عملکرد ستون به منظور استخراج یون‌های توریم از محلول آبی انجام گردید. اثر پارامترهای عملیاتی بر شرایط هیدرودینامیکی ستون مورد تحقیق قرار گرفت. نتایج نشان داد که افزایش پارامترهای عملیاتی شامل سرعت اختلاط، سرعت فاز پراکنده و سرعت فاز پیوسته با افزایش در درصد استخراج توریم همراه است. بیشینه درصد استخراج 97/54% در سرعت اختلاط برابر با 220rpm و سرعت‌های فاز پراکنده و فاز پیوسته برابر با mm/s 0/66 حاصل گردید. افزایش سرعت اختلاط موجب کاهش اندازه قطره و توزیع باریک‌تر از اندازه قطرات می‌گردد. با افزایش سرعت فاز پیوسته در شرایط ثابت برای سایر پارامترها، مقاومت در برابر حرکت قطرات فاز پراکنده ایجاد می‌شود و سرعت لغزشی کاهش می‌یابد.

کلیدواژه‌ها

عنوان مقاله [English]

Investigation of hydrodynamic parameters in a packed-agitated extraction column for the extraction of thorium ions from aqueous solution

نویسندگان [English]

  • M. Asadollahzadeh
  • R. Torkaman
  • M. Torab-Mostaedi

Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, AEOI, P.O.Box: 11365-8486, Tehran - Iran

چکیده [English]

This research evaluates the hydrodynamic behavior of a packed-agitated column, which includes agitated and irregularly packed sections, for extracting thorium ions from an aqueous solution. The effects of various operating parameters on the column's hydrodynamic conditions were investigated. Results indicate that increasing operating parameters such as agitation speed, dispersed phase velocity, and continuous phase velocity enhances thorium extraction efficiency. The maximum extraction efficiency achieved was 97.54% at an agitation speed of 220 rpm, with dispersed and continuous phase velocities of 0.66 mm/s. Increasing the agitation speed results in smaller droplet sizes and a narrower droplet size distribution. Additionally, an increase in continuous phase velocity, while keeping other parameters constant, creates resistance to the movement of dispersed phase droplets, leading to a decrease in slip velocity.

کلیدواژه‌ها [English]

  • Liquid-liquid extraction
  • Packed-agitated column
  • Thorium
  • Operating parameters
  • Hydrodynamic condition
  1. Yu X, Zhou H, Jing S, Lan W, Li S. Experimental and numerical study of liquid–liquid interphase mass transfer in a pilot-scale extraction column. Chem. Eng. Sci. 2021;230:116184.

 

  1. Asadollahzadeh M, Torkaman R, Torab-Mostaedi M. Optimization of lanthanum extraction in asymmetric rotation pilot plant column by using central composite methodology. Geosystem Eng. 2020;23:101-111.

 

  1. Asadollahzadeh M, Torkaman R, Torab-Mostaedi M, Heydari A. Feasibility of pilot-scale disc-donut column for continuous cadmium extraction with the perspective of droplet size distribution. Geosystem Eng. 2021;24:265-274.

 

  1. Shakib B, Asadollahzadeh M, Outokesh M, Torkaman R, Torab-Mostaedi M. Reactive extraction evaluation for vanadium (V) removal in the MRDC column using axial dispersion and central composition approach. Korean J. Chem. Eng. 2022;39:3399-3411.

 

  1. Saremi M, Torkaman R, Safdari J, Rafiei V, Mallah M.H, Asadollahzadeh M. Determination of mass transfer coefficient in an L-shaped pulsed column with sieve-plate structure: Application of best-fit technique, drop size distribution, and forward mixing model. Chem. Eng. Process. 2022;170:108706.

 

  1. Sarkar S, Sen N, Singh K.K, Mukhopadhyay S, Shenoy K.T. Liquid-liquid dispersion in pulsed disc and doughnut column and pulsed sieve plate column: A comparative study. Prog. Nucl. Energy. 2019;116:76-86.

 

  1. Shakib B, Ghaemi A, Hemmati A, Asadollahzadeh M. Experimental modeling and uncertainty analysis of dispersed phase holdup at flooding in a pulsed disc-doughnut column, case study: Response surface methodology and Monte-Carlo simulation. Prog. Nucl. Energy. 2021;141:103969.

 

  1. Yi H, Smith K.H, Fei W, Stevens G.W. CFD Simulation of Two-Phase Flow in a Hybrid Pulsed Sieve-Plate Solvent Extraction Column: Prediction of Holdup and Axial-dispersion Coefficients. Solvent Extract. Ion Exch. 2020;38:88-102.

 

  1. Sovilj M.N, Nikolovski B.G, Spasojević M.Đ. Hydrodynamics in spray and packed liquid-liquid extraction columns: A review. Mac. J. Chem. Chem. Eng. 2019;38:267-282.

 

  1. Thornton J.D. Science and Practice in liquid-Liquid Extraction Column. Clarendon Press, New York. 1992.

 

  1. Lo T.C, Baird M.H.I, Hanson C. Handbook of Solvent Extraction. Krieger Pub Co, New York. 1992.

 

  1. Asadollahzadeh M, Torkaman R, Torab-Mostaedi M. Assessment of population balance approach and maximum entropy on drop size behavior of vanadium extraction from sulfate solution in continuous pilot plant column. Chem. Eng. Process. 2021;169:108608.

 

  1. Asadollahzadeh M, Torkaman R, Torab-Mostaedi M, Moazami F. Estimation of performance with the two truncated probability density functions, case study: using mixco column to extract samarium and gadolinium. Sep. Sci. Technol. 2021;56:1241-1252.

 

  1. Asadollahzadeh M, Torkaman R, Torab-Mostaedi M, Saremi M. Removal of cerium ions in pilot scale agitated column with sieve structure, case study: Evaluation of mass transfer models. Inter. J. Heat Mass Trans. 2022;188:122638.

 

  1. Shakib B, Torkaman R, Torab-Mostaedi M, Saremi M, Asadollahzadeh M. Performance evaluation during extraction technique in modified rotating disc column: Experimental and mathematical modeling. Chem. Eng. Process. 2022;171:108762.

 

  1. Shakib B, Torkaman R, Saremi M, Torab-Mostaedi M, Asadollahzadeh M. Reactive extraction of zinc ions in the Scheibel column; A case study by applying the mathematical modelling of mass transfer with forward mixing. Chem. Eng. Process. 2021;169:108606.

 

  1. Sert Ş, Yusan S. Extraction and separation of thorium from cerium and lanthanum by Cyphos® IL 101 ionic liquid. J. Radioanal. Nucl. Chem. Article in Press. 2023.

 

  1. Deshmukh S, Bhatt A.M, Boda A, Chauhan R.S, Ali S.M, Sengupta A. Experimental and theoretical insight into biphasic extractive mass transfer of thorium into ionic liquid phase using chloroamide ligands. J. Mol. Liq. 2023;371:121074.

 

  1. Zeng Z, Gao Y, Ni S, Zhang S, Fu X, Sun X. Investigation on the recovery of thorium and rare earth from radioactive waste residue by functionalized ionic liquids. Sep. Purif. Technol. 2023;317:123901.

 

  1. Wang H, Kuang S, Liao W. Synergistic extraction and separation of thorium from rare earths in chloride media using mixture of Cextrant 230 and Cyanex 923. J. Rare Earths. 2023.

 

  1. Yacouba A.-R.C, Oral A.E, Bawa A.S, Sert S, Kaptanoglu I.G, Turkozu D.A, Natatou I, Yusan S, Aytas S. Determination of optimum conditions for the extraction and separation of lanthanum, cerium, yttrium and thorium using Taguchi method. J. Radioanal. Nucl. Chem. Article in Press. 2023.

 

  1. Sarkar S, Phillips C.R, Mumford C.J. Characterization of hydrodynamic parameters in rotating disc and oldshue-rushton columns, hydrodynamic modelling, drop Size, hold-up and flooding. Can. J. Chem. Eng. 1985;63:701-709.

 

  1. Tsouris C, Ferreira R, Tavlarides L.L. Characterization of hydrodynamic parameters in a multistage column contactor. Can. J. Chem. Eng. 1990;68:913-923.